Yes, there will be a couple of different ways. Employers will eventually be able to look directly into the pool through the job bank. Applicants in the pool will be required to register with the job bank. Employers who are unable to locate first a Canadian citizen or permanent resident to fill a job will be able to make a job offer through the labour market impact assessment process operated by ESDC.
Conversely, an employer who already has identified someone abroad could invite that person to submit their expression of interest into the express entry pool and access the employee that way; or if the employer wishes to make a temporary foreign worker a permanent job offer, they could invite that employee to submit their expression of interest and be accommodated through that pathway.